Product ID:CLC-1000 TONER BLACK, F42-0503-700
MSDS Date:12/01/1996
FSC:6850
NIIN:00N088165
MSDS Number: CHLSD

CANON USA INC

ONE CANON PLAZA
LAKE SUCCESS, NY 11042
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 516-328-5600

Cage: 1BA63

CANON USA INC

LAKE SUCCESS, NY 11042 US

Telephone: 516-328-5600

Cage: 1BA63

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 1-5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9495

BISPHENOL A PROPYLENE OXIDE FUMARATE; (POLYESTER RESIN)

CAS: 39382-25-7

Fraction By Weight: 85-95%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50 (ORAL, RAT): >5000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MINIMAL RESPIRATORY TRACT
IRRITATION MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY
NON-TOXIC DUST. INGESTION: INGESTION IS NOT APPLICABLE ROUTE OF
ENTRY FOR INTENDED USE. EYE: MAY CAU SE EYE IRRITATION. SKIN:
UNLIKELY TO CAUSE SKIN IRRITATION. CHRONIC: PROLONGED INHALATION OF
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOL 65,
PG 24-27, 1995: GROUP 2B.
Effects of Overexposure:HLTH HAZ: EXCESSIVE DUST MAY CAUSE LUNG DAMAGE,
ATTRIBUTED TO LUNG OVERLOADING, GENERIC RESPONSE TO EXCESSIVE
AMOUNTS OF ANY DUST RETAINED IN THE LUNG FOR A PROLONGED INTERVAL.
USE OF THIS PRODUCT AS INTENDED, IN ACCORDANCE W/PROVISION OF THIS
MATERIAL SAFETY DATA SHEET DOES NOT RESULT IN INHALATION OF
EXCESSIVE DUST.
Medical Cond Aggravated by Exposure:NOT DETERMINED.

First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. GET MEDICAL ATTENTION
IF SYMPTOMS PERSIST. INGESTION: DILUTE STOMACH CONTENTS WITH
SEVERAL GLASSES OF WATER. GET MEDICAL ATTENTION IF SYMPTOMS
PERSIST. EYE: FLU SH WITH RUNNING WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION PERSIST, GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND
WATER. IF IRRITATION PERSISTS GET MEDICAL ATTENTION. NOTE TO
PHYSICIANS: NONE.

Extinguishing Media:CO*2, WATER, DRY CHEMICALS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:TONER MATERIAL LIKE MOST ORGANIC MATERIAL
IN POWDER FORM IS CAPABLE OF CREATING A DUST EXPLOSION.

Spill Release Procedures:PERS PREC: AVOID BRTHG DUST. USE W/ADEQ VENT.
ENVIRONMENTAL PRECS: DO NOT WASH AWAY INTO SEWER. METHOD FOR
CLEANING UP: SWEEP MATL ONTO PAPER & CAREFULLY TRANSFER TO A
SEALABLE WASTE CNTNR. IF A VACUU M IS USED MOTOR MUST BE RATED AS
DUST (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID BREATHING DUST. USE WITH
ADEQUATE VENTILATION. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM
CONTACT WITH OXIDIZING MATERIALS.
Other Precautions:KEEP CONTAINER CLOSED.

Respiratory Protection:NOT REQUIRED. NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT UNDER
INTENDED USE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPILL PROC: TIGHT. A CONDUCTIVE HOSE BONDED TO THE MACHINE SHOULD BE
USED TO REDUCE STATIC BUILDUP.

Melt/Freeze Pt:M.P/F.P Text:>212F,>100C
Spec Gravity:4.0-5.0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK FINE POWDER; SLIGHT PLASTIC ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE
AND POSSIBLY TOXIC CHEMICALS SUCH AS CARBON MONOXIDE.

Waste Disposal Methods:WASTE TONER COULD BE CONSIDERED AS PLASTIC
POWDER WASTE. FOR INCINERATION, PACKAGE IT ADEQUATE. DO NOT
DISPERSE THE TONER INTO FIRE. THE WASTE CARRIER COULD BE CONSIDERED
AS WASTE METAL. DISPOSAL SHOU LD BE SUBJECT TO FEDERAL, STATE AND
LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.